📋 Structured Questions
These questions test key concepts from Section 2. Attempt each question on paper, then click "Show Mark Scheme" to check your answer.
Question 1: Group 1 & Group 7 Properties
4 marks(a) Describe two observations when a small piece of sodium is added to water. [2]
(b) State the color of liquid bromine at room temperature and the observation when bromine water is added to potassium iodide solution. [2]
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(a)
Any two observations from:
- Sodium floats / moves on the surface [1]
- Sodium melts into a sphere / ball [1]
- Effervescence / fizzing / bubbles of gas [1]
- Sodium gets smaller and disappears / dissolves [1]
(b)
- Color of bromine: Red-brown [1]
- Observation: The solution turns brown (due to displacement forming iodine) [1]
Question 2: Percentage of Oxygen in Air
4 marks(a) Describe a laboratory experiment using copper turnings that can be used to determine the percentage by volume of oxygen in air. [4]
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- Place a known volume of air (e.g. 100 cm3) in one gas syringe and pass it back and forth over heated copper turnings in a glass tube [1]
- Heat the copper strongly using a Bunsen burner [1]
- Continue passing the air over the copper until the volume of air stops decreasing / remains constant [1]
- Allow the apparatus to cool to room temperature, measure the final volume of gas, and calculate the percentage decrease in volume [1]
Question 3: Displacement & Redox
4 marks(a) Write a balanced chemical equation (including state symbols) for the displacement reaction between solid iron and aqueous copper(II) sulfate. [1]
(b) Explain, in terms of electrons, why this displacement reaction is classified as a redox reaction. [3]
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(a)
Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s)[1]
(b)
- Iron atoms lose electrons (to form Fe2+ ions) and are oxidized [1]
- Copper(II) ions (Cu2+) gain electrons (to form copper atoms) and are reduced [1]
- Since both oxidation and reduction occur at the same time, the reaction is redox [1]
Question 4: Metal Extraction in the Blast Furnace
3 marks(a) In the blast furnace, iron(III) oxide (Fe2O3) is reduced to iron. Explain the role of carbon monoxide in this reduction. Include a balanced symbol equation. [3]
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- Carbon monoxide acts as the reducing agent / reduces the iron(III) oxide [1]
- It removes oxygen from iron(III) oxide to form carbon dioxide and iron [1]
- Equation:
Fe2O3 + 3CO → 2Fe + 3CO2[1]
Question 5: Preparing Copper(II) Sulfate
4 marks(a) Describe how a student can prepare a pure, dry sample of hydrated copper(II) sulfate crystals starting from solid copper(II) oxide and dilute sulfuric acid. [4]
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- Add solid copper(II) oxide in excess to warm dilute sulfuric acid until no more dissolves [1]
- Filter the mixture to remove the unreacted copper(II) oxide solid [1]
- Heat the copper(II) sulfate filtrate solution in an evaporating basin to evaporate some water until a saturated solution is formed / crystallisation point is reached [1]
- Leave the solution to cool and crystallise, then filter the crystals and pat them dry with filter paper [1]
Question 6: Chemical Analysis
6 marks(a) A student is given a bottle containing a green solid X. Describe the chemical tests the student can perform to identify the cation and the anion present in solid X. State the expected observations. [6]
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Indicative content:
- Cation Test (Copper(II) ions, Cu2+):
- Method 1 (Flame test): Dip a clean wire loop into hydrochloric acid, then into solid X and hold in a blue Bunsen burner flame. Observation: Green / blue-green flame.
- Method 2 (Sodium hydroxide test): Dissolve solid X in water to make a solution. Add aqueous sodium hydroxide (NaOH). Observation: Blue precipitate of copper(II) hydroxide.
- Anion Test (Carbonate ions, CO3 2-):
- Method: Add dilute hydrochloric acid (HCl) to solid X or a solution of X. Observation: Effervescence / bubbles of gas.
- Confirmation: Bubble the gas produced through limewater. Observation: Limewater turns cloudy / milky.
Marking guidance:
- 5 to 6 marks: Describes valid chemical tests and correct observations for both the cation and the anion. Includes details of reagents used and gas confirmation if applicable.
- 3 to 4 marks: Describes a valid test and observation for either the cation or the anion, or describes tests for both but with incorrect/missing observations.
- 1 to 2 marks: Simple statements identifying one reagent or one correct observation.