IB Chemistry 1.3 1.3.4
1.3.4
Structure 1.3 SL & HL ⏱️ ~4 min revision

Sublevels & Orbitals

Atomic orbitals, subshell structure (s, p, d, f), and 3D probability shapes.

Main energy levels (n) are split into sub-levels (s, p, d, f). Each sub-level contains orbitals - regions of space where there is a high probability of finding an electron. Each individual orbital holds a maximum of 2 electrons.

Orbital Definition

Atomic Orbitals

An atomic orbital is a region of space around the nucleus where there is a high probability of finding an electron (typically defined as >90% probability). Each individual orbital can hold a maximum of two electrons with opposite spins.

s-orbitals

Spherical Shape

Sublevel Capacity

Sublevel Structure & Capacities

  • s sublevel: 1 orbital → max 2 electrons
  • p sublevel: 3 degenerate orbitals (px, py, pz) → max 6 electrons
  • d sublevel: 5 degenerate orbitals → max 10 electrons
  • f sublevel: 7 degenerate orbitals → max 14 electrons

p-orbitals

Dumbbell Shape

Total Sublevel Capacities

s-sublevel2 e⁻
p-sublevel6 e⁻
d-sublevel10 e⁻
f-sublevel14 e⁻
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Orbital Energy Levels & Aufbau Principle

Electrons fill the lowest available energy sublevels first. Notice that the 4s sublevel is slightly lower in energy than the 3d sublevel, so it fills first. When orbitals have the same energy (degenerate), they fill singly first (Hund's rule).

Orbital Energy Diagram (Example: Iron, Fe)

Orbital Energy Diagram ENERGY s p d 1s 2s 2p 3s 3p 4s 3d 4p Notice 4s fills BEFORE 3d Hund's Rule in 3d Orbitals fill singly with parallel spins before pairing.