IB ChemistryStructure 33.13.1.3
3.1.3

Metallic & Non-Metallic Character

How element character changes across periods and the acid-base nature of oxides.

Metallic character decreases across a period (left → right) and increases down a group. This mirrors the trends in ionisation energy – metals lose electrons easily.

Oxide Acid-Base Character Across Period 3

Oxide Na₂O MgO Al₂O₃ SiO₂ P₄O₁₀ SO₃ Cl₂O₇
Character Basic Basic Amphoteric Weakly acidic Acidic Strongly acidic Strongly acidic
Bonding Giant ionic Ionic/covalent Giant covalent Simple molecular

🔑 Pattern

Metal oxides are basic (react with acids). Non-metal oxides are acidic (react with bases / dissolve in water to form acids). Al₂O₃ is the classic amphoteric oxide – it reacts with both acids and bases.

⚠️ Examiner Trap

Students frequently call Al₂O₃ a "neutral" oxide. It is amphoteric, not neutral. Amphoteric = reacts with both acids and bases. Neutral = reacts with neither.

← 3.1.2 Periodic Trends3.1.4 Group 1 & 17 →