IB ChemistryStructure 33.23.2.1
3.2.1

Types of Formula

Empirical, molecular, structural, condensed, and skeletal. Different ways to represent the same molecule.

Formula Type Shows Ethanol Example
Empirical Simplest whole-number ratio C₂H₆O
Molecular Actual number of each atom C₂H₆O
Full structural Every bond drawn explicitly H–C–C–O–H (with all H)
Condensed Groups written sequentially CH₃CH₂OH
Skeletal C–C backbone as zig-zag; H on C omitted Line with –OH at end

⚠️ Examiner Trap

In a full structural formula, every single bond must be drawn, including those within functional groups. Writing "–OH" instead of "–O–H" will lose the mark. If the question says "structural formula," draw all bonds.

⚠️ Hidden Hydrogens in Skeletal Formulas

When interpreting skeletal structures, remember carbon always has 4 bonds. Count the drawn bonds at each vertex/end and add implicit H atoms to reach 4. Forgetting this leads to wrong molecular formulas.

⚠️ Functional Group Connectivity

Draw –COOH connected through the carbon atom, not through the H. Writing the carboxylic acid group backwards (HOOC–) or connecting through the wrong atom loses marks. The same applies to alcohols: write C–O–H, never C–HO.

← Back to 3.23.2.2 Functional Groups →