IB Chemistry R3.2 R3.2.16
R3.2.16 HL

Electroplating & Applications

Practical uses of electrolysis including electroplating setup.

Electroplating

The use of electrolysis to coat an object with a thin layer of metal, for corrosion resistance, appearance, or wear resistance.

Electroplating Setup

ComponentWhat to UseWhy
Cathode (-)Object to be platedMetal ions are reduced onto its surface
Anode (+)Pure plating metalDissolves to replenish metal ions in solution
ElectrolyteSolution of plating metal saltProvides the metal ions (e.g., CuSO₄ for copper plating)

Applications of Electrolysis

ApplicationDetails
ElectroplatingChromium/nickel plating of cutlery, taps, jewellery
Aluminium extractionHall-Heroult process: electrolysis of Al₂O₃ in molten cryolite
Chlor-alkali industryElectrolysis of brine producing Cl₂, H₂, and NaOH
Copper purificationImpure Cu anode dissolves; pure Cu deposited at cathode

📋 Exam Tip

In electroplating, the object to be plated is always the cathode. Remember: the plating metal is reduced onto the cathode surface (PANIC: Positive Anode, Negative Is Cathode).

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