IB Chemistry R3.2 R3.2.5
R3.2.5

Oxidising & Reducing Agents

Identifying which species gains electrons and which loses them in a redox reaction.

📘 IB Understanding

An oxidising agent accepts electrons (gets reduced). A reducing agent donates electrons (gets oxidised). Use the mnemonic OIL RIG: Oxidation Is Loss, Reduction Is Gain.

Key Definitions

TermWhat It DoesWhat Happens to It
Oxidising agentCauses oxidation in another speciesGets reduced (gains e-)
Reducing agentCauses reduction in another speciesGets oxidised (loses e-)

Example: Halogen Displacement

Cl2(aq) + 2Br-(aq) → 2Cl-(aq) + Br2(aq)

Identifying the Agents

  • Cl2 gains electrons (0 → -1): it is the oxidising agent
  • Br- loses electrons (-1 → 0): it is the reducing agent

Writing Half-Equations

Splitting the Reaction

  • Reduction: Cl2 + 2e- → 2Cl-
  • Oxidation: 2Br- → Br2 + 2e-

⚠️ Exam Tip

When identifying agents, always name the entire substance (e.g. "chlorine" or "bromide ions"), not just the atom.

← R3.2.4 Oxidation NumbersR3.2.6 Voltaic Cells →