IB Chemistry R3.2 R3.2.6
R3.2.6

Voltaic Cells

Converting chemical energy to electrical energy using spontaneous redox reactions.

📘 IB Understanding

A voltaic (galvanic) cell converts the energy from a spontaneous redox reaction into electrical energy. It consists of two half-cells connected by an external wire and a salt bridge.

Voltaic Cell (Zn/Cu)

Zinc-copper voltaic cell ZnSO₄(aq) CuSO₄(aq) Zn Cu ANODE (−) CATHODE (+) e⁻ flow → V Salt Bridge Zn → Zn²⁺ + 2e⁻ Cu²⁺ + 2e⁻ → Cu

Key Components

ComponentFunction
Anode (−)Oxidation occurs, electrons leave here
Cathode (+)Reduction occurs, electrons arrive here
Salt bridgeCompletes circuit; allows ion flow to balance charges
External wireAllows electron flow generating current

Cell Notation (IUPAC)

Zn(s) | Zn2+(aq) || Cu2+(aq) | Cu(s)

Anode on the left, cathode on the right. | = phase boundary, || = salt bridge.

⚠️ Exam Tip

Remember: AN OX (anode = oxidation), RED CAT (reduction = cathode). In voltaic cells, electrons flow from anode to cathode through the external circuit.

← R3.2.5 Oxidising AgentsR3.2.7 Electrode Potentials →